Panels have to face the sun to draw power. You get the energy from the sun, so it's important for the panels to be located in an area where they can get all the solar energy possible.
If you want to have a solar system installed on your roof, make sure you check the credentials of anyone working on your home. Check certifications, verify references and generally research the company prior to signing any contract. This is a big investment, so make sure that you choose a reputable company.
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Experiment with various angles and placements, monitoring the power stored on a daily basis and making changes as necessary. Any angle might be acceptable, but there are times when a small tweak in the position can have a noticeable impact. Try different options and stick with the spot that works best.